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dc.contributor.authorLodeiro, Pablo
dc.contributor.authorRey Castro, Carlos
dc.contributor.authorDavid, Calin
dc.contributor.authorAchterberg, Eric P.
dc.contributor.authorPuy Llorens, Jaume
dc.contributor.authorGledhill, Martha
dc.description.abstractMarine dissolved organic matter (DOM) plays a key role in the current and future global carbon cycle, which supports life on Earth. Trace metals such as iron, an essential micronutrient, compete with protons and major ions for the binding to DOM. These competitive effects and the DOM binding capacity are related to the DOM acid-base properties, which also influence DOM transport and reactivity in marine waters. Here we present the results of a complete set of acid-base titration experiments of a pre-concentrated marine DOM sample in the range 0.01 ≤ I ≤ 0.7 M and 3 ≤ pH ≤ 10. We characterize the obtained proton binding curves using a combination of the non-ideal competitive adsorption (NICA) isotherm and Donnan electrostatic model. Within the main chemical groups of marine DOM, the carboxylic distribution was accurately characterized from the obtained data (QmaxH, 1=2.52 mol·kg−1, = 3.26, m1 = 0.69 and b = 0.70). This carboxylic mode was found to be less acidic and more homogeneous than a generic fulvic acid, but the differences are consistent with the reported variability of fulvic acids of freshwater and terrestrial origin. We find that changes in temperature (down to 5.5 °C), and the presence of calcium or magnesium (at 0.01 M) resulted in no significant modification of the proton ion binding curves obtained at 25 °C and 0.7 or 0.1 M ionic strength, respectively. We demonstrate the relevance of proton binding parameters for the modelling of the system iron/marine DOM throughout a wide range of salinity and acidity conditions in the context of different future ocean scenarios.ca_ES
dc.description.sponsorshipThe authors gratefully acknowledge support from the Deutsche Forschungsgemeinschaft (Project GL 807/2), the Spanish Ministerio de Economía y Competitividad (Project CTM2016-78798-C2-1-P) and the German Helmholtz Association.ca_ES
dc.relation.isformatofVersió postprint del document publicat a:
dc.relation.ispartofScience of The Total Environment, 2020, vol. 729, p. 138437ca_ES
dc.rightscc-by-nc-nd, (c) Elsevier, 2020ca_ES
dc.subjectMarine DOMca_ES
dc.subjectProton bindingca_ES
dc.subjectIntrinsic pKaca_ES
dc.subjectTrace metal availabilityca_ES
dc.titleAcid-base properties of dissolved organic matter extracted from the marine environmentca_ES

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cc-by-nc-nd, (c) Elsevier, 2020
Except where otherwise noted, this item's license is described as cc-by-nc-nd, (c) Elsevier, 2020