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dc.contributor.authorAissou, Mohamed
dc.contributor.authorChemat-Djenni, Zoubida
dc.contributor.authorYara Varón, Edinson
dc.contributor.authorFabiano-Tixier, A. S.
dc.contributor.authorChemat, F.
dc.date.accessioned2020-11-04T10:05:47Z
dc.date.available2020-11-04T10:05:47Z
dc.date.issued2016-06-28
dc.identifier.issn1631-0748
dc.identifier.urihttp://hdl.handle.net/10459.1/69769
dc.description.abstractThe objective of this study was to transform limonene as an agro-chemical platform for the production of a wide range of added-value compounds for pharmaceutical, cosmetic and food ingredients. This molecule was also evaluated as an alternative solvent for the extraction of several bioactive compounds compared to n-hexane. Limonene was extracted from the essential oils of orange peels through a solvent-free microwave extraction technique. Limonene was successfully transformed into products with industrial interest by catalytic oxidation using three different iron catalysts. The ability of limonene to be used as an alternative solvent was performed using two simulation tools, Hansen solubility parameters (HSPs) and the Conductor-like Screening Model for Real Solvents (COSMO-RS), and via experimentation. The results indicated that limonene could be a promising green solvent and synthon for petroleum substitution in the extraction or synthesis of bioactive compounds.ca_ES
dc.description.abstractL'objectif de cette étude est de montrer les potentialités du limonène comme une plateforme agrochimique pour la production d'une large gamme de composés à valeur ajoutée pour les industries pharmaceutique, cosmétique et agroalimentaire. Cette molécule a été évaluée en tant que synthon pour la synthèse de molécules bioactives et comme solvant alternatif à l'hexane pour l'extraction de composés bioactifs. Deux outils de simulation solvant--soluté ont été utilisés pour simuler et optimiser les potentialités du limonène : les paramètres de solubilité Hansen (HSP) et le modèle « Conductor-like Screening Model for Real Solvents » (COSMO-RS). Les résultats indiquent que le limonène peut être un solvant vert et un synthon prometteur pour la substitution du pétrole dans l'extraction ou la synthèse de composés bioactifs.ca_ES
dc.description.sponsorshipThis work was supported in part thanks to funding from the fellowship given to Edinson Yara Varón (No. TECSPR14-2-0029) from the People Programme (Marie Curie Actions) of the Seventh Framework Programme of the European Union (FP7/2007-2013) under REA grant agreement no. 600388 (TECNIOspring programme), and from the Agency for Business Competitiveness of the Government of Catalonia, ACCIÓ.ca_ES
dc.language.isoengca_ES
dc.publisherAcadémie des sciencesca_ES
dc.publisherElsevierca_ES
dc.relation.isformatofReproducció del document publicat a: https://doi.org/10.1016/j.crci.2016.05.018ca_ES
dc.relation.ispartofComptes Rendus Chimie, 2017, vol. 20, núm. 4, p. 346-358ca_ES
dc.rightscc-by-nc-nd (c) Académie des sciences, 2016ca_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectLimoneneca_ES
dc.subjectBuilding blockca_ES
dc.subjectSolventca_ES
dc.subjectOxidationca_ES
dc.titleLimonene as an agro-chemical building block for the synthesis and extraction of bioactive compoundsca_ES
dc.title.alternativeUtilisation du limonène comme synthon agrochimique pour la synthèse et l'extraction de produits naturelsca_ES
dc.typeinfo:eu-repo/semantics/articleca_ES
dc.type.versioninfo:eu-repo/semantics/publishedVersionca_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessca_ES
dc.identifier.doihttps://doi.org/10.1016/j.crci.2016.05.018
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/600388ca_ES


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Except where otherwise noted, this item's license is described as cc-by-nc-nd (c) Académie des sciences, 2016