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dc.contributor.authorCanela Xandri, Anna
dc.contributor.authorVillorbina Noguera, Gemma
dc.contributor.authorBalcells Fluvià, Mercè
dc.contributor.authorFernández Francos, Xavier
dc.contributor.authorCabeza, Luisa F.
dc.contributor.authorCanela i Garayoa, Ramon
dc.date.accessioned2019-11-04T07:53:18Z
dc.date.available2019-11-04T07:53:18Z
dc.date.issued2019
dc.identifier.issn1420-3049
dc.identifier.urihttp://hdl.handle.net/10459.1/67442
dc.description.abstractNine monoamides were synthesized from carboxylic acids (C8-C18) and crude glycerol. The final monoamides were the result of a rearrangement of the acyl chain during the final hydrogenation process. The purity of the final compounds was determined by spectroscopic and mass spectrometry (MS) techniques. The thermophysical properties of solid monoamides were investigated to determine their capability to act as phase change materials (PCM) in thermal energy storage. Thermophysical properties were determined with a di erential scanning calorimeter (DSC). The melting temperatures of the analyzed material ranged from 62.2 C to 116.4 C. The analyzed enthalpy of these monoamides ranged from 25.8 kJ/kg to 149.7 kJ/kg. Enthalpy values are analyzed considering the carbon chain and the formation of hydrogen bonds.
dc.description.sponsorshipThis work was partially funded by the Ministerio de Ciencia, Innovación y Universidades de España (grants: MINECO/FEDER CTQ2015-70982-C3-1-R and MINECO/FEDER RTI2018-093849-B-C31). This work is partially supported by ICREA under the ICREA Academia programme. Acknowledgments: R.C.-G. and L.F.C. would like to thank the Catalan Government for the quality accreditation given to their research groups (grants 2017 SGR 828 and GREiA 2017 SGR 1537, respectively). DBA and GREiA are certified agent TECNIO in the category of technology developers from the Government of Catalonia.
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherMDPI
dc.relationMINECO/PN2013-2016/CTQ2015-70982-C3-1-R
dc.relationMINECO/PN2013-2016/RTI2018-093849-B-C31
dc.relation.isformatofReproducció del document publicat a: https://doi.org/10.3390/molecules24203777
dc.relation.ispartofMolecules, 2019, vol. 24, p. 3777-1-3777-10
dc.rightscc-by (c) Canela Xandri, Anna et al., 2019
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es
dc.subjectAlkyl monoamides
dc.subjectGlycerol
dc.subjectHydrogen bond
dc.subjectPCM
dc.subjectTES
dc.titleSynthesis and Thermophysical Characterization of Fatty Amides for Thermal Energy Storage
dc.typeinfo:eu-repo/semantics/article
dc.date.updated2019-11-04T07:53:19Z
dc.identifier.idgrec029109
dc.type.versioninfo:eu-repo/semantics/publishedVersion
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.identifier.doihttps://doi.org/10.3390/molecules24203777


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cc-by (c) Canela Xandri, Anna et al., 2019
Except where otherwise noted, this item's license is described as cc-by (c) Canela Xandri, Anna et al., 2019