Show simple item record

dc.contributor.authorEscribà i Gelonch, Marc
dc.contributor.authorEras i Joli, Jordi
dc.contributor.authorBalcells Fluvià, Mercè
dc.contributor.authorCanela i Garayoa, Ramon
dc.date.accessioned2016-11-09T09:32:22Z
dc.date.issued2013
dc.identifier.issn2046-2069
dc.identifier.urihttp://hdl.handle.net/10459.1/58433
dc.description.abstractAs part of our continued effort to achieve the synthesis of halohydrin esters from polyols by a sustainable method, here we report on a multicomponent inorganic acid-mediated solvent-free synthesis. The synthesis was designed to ensure few waste materials. Using this approach, the process shows a low E-factor and a high reaction mass efficiency. The new process involves the preparation of a reaction mixture containing either a fatty acid or fatty material, glycerol or diol, a halide salt and H3PO4. This mixture is heated at 100 °C for 48 h, yielding up to 88% of halohydrin ester. The process also allows recovery of pyrophosphate salts, compounds that have various applications in agriculture, and in the pharmaceutical, chemical and food industries.ca_ES
dc.description.sponsorshipThis work was supported in part by a Grant-in-Aid from the Secretarı´a de Estado de Polı´tica Cientı´fica y Tecnolo´gica of the Spanish Ministry of Education and Culture (Contract grant number: CTQ2009-14699-C02-01).ca_ES
dc.language.isoengca_ES
dc.publisherRoyal Society of Chemistryca_ES
dc.relationMICINN/PN2008-2011/CTQ2009-14699-C02-01ca_ES
dc.relation.isformatofReproducció del document publicat a https://doi.org/10.1039/C3RA41715Hca_ES
dc.relation.ispartofRSC Advances, 2013, vol. 3, núm. 23, p. 8805-8810ca_ES
dc.rights(c) Royal Society of Chemistry, 2013ca_ES
dc.subject.otherQuímica orgànicaca_ES
dc.subject.otherCatàlisica_ES
dc.subject.otherÈstersca_ES
dc.titleH3PO4/metal halide induces a one-pot solvent-free esterification–halogenation of glycerol and diolsca_ES
dc.typearticleca_ES
dc.identifier.idgrec019642
dc.type.versionpublishedVersionca_ES
dc.rights.accessRightsinfo:eu-repo/semantics/restrictedAccessca_ES
dc.identifier.doihttps://doi.org/10.1039/C3RA41715H
dc.date.embargoEndDate10000-01-01


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record