Glycerol as a starting material to prepare palmitate derivatives
Fecha de publicación2007
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Glycidyl palmitate, used to obtain high purity monoglycerides and epoxy resins, can be obtained from glycerol using a two-step process. The first step of this new approach consists in a reaction of esterification-chlorination of glycerol. An elimination reaction using Cs2CO3 allows the corresponding
glycidyl ester to be prepared from the chlorohydrin ester intermediate.
Es parte deAfinidad, 2007, vol. 64, núm. 528, p. 203-206
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Canela Xandri, Anna; Balcells Fluvià, Mercè; Villorbina Noguera, Gemma; Christou, Paul; Canela i Garayoa, Ramon (MDPI, 2020-05-28)Crude glycerol (C3H8O3) is a major by-product of biodiesel production from vegetable oils and animal fats. The increased biodiesel production in the last two decades has forced glycerol production up and prices down. ...
Villorbina Noguera, Gemma; Tomàs, Albert; Escribà i Gelonch, Marc; Oromí Farrús, Mireia; Eras i Joli, Jordi; Balcells Fluvià, Mercè; Canela i Garayoa, Ramon (Elsevier, 2009)We describe here the first example in which glycerol has been transformed into chlorohydrin esters using an ionic liquid and hydrated aluminium chloride. The method avoids using Crown-18 ether, which was needed to obtain ...
Solarte Orozco, Carmen Eugenia; Escribà i Gelonch, Marc; Eras i Joli, Jordi; Villorbina Noguera, Gemma; Canela i Garayoa, Ramon; Balcells Fluvià, Mercè (Molecular Diversity Preservation International, 2011)The anticipated worldwide increase in biodiesel production will result in an accumulation of glycerol for which there are insufficient conventional uses. The surplus of this by-product has increased rapidly during the last ...