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dc.contributor.authorPuy Llorens, Jaume
dc.contributor.authorCecilia Averós, Joan
dc.contributor.authorGalceran i Nogués, Josep
dc.contributor.authorTown, Raewyn M.
dc.contributor.authorLeeuwen, Herman P. van
dc.date.accessioned2015-11-10T10:41:39Z
dc.date.available2015-11-10T10:41:39Z
dc.date.issued2004
dc.identifier.issn1572-6657
dc.identifier.urihttp://hdl.handle.net/10459.1/48940
dc.description.abstractThe voltammetric lability of a complex system, where a metal ion M and a ligand L form the species ML and ML2, is examined. Together with the rigorous numerical simulation of the problem, two limiting cases are analysed for the overall process ML2 → M: (i) the most common case for aqueous complexes, where ML → M is the kinetically limiting step and (ii) the case where ML2 → ML is limiting. In both cases, analytical expressions for the lability criteria are provided which show good agreement with the results obtained from the rigorous numerical simulation of the problem.
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherElsevier
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1016/j.jelechem.2004.04.017
dc.relation.ispartofJournal of Electroanalytical Chemistry, 2004, vol. 571, num. 2, p. 121-132
dc.rights(c) Elsevier, 2004
dc.subject.classificationVoltametria
dc.subject.classificationMetalls
dc.subject.otherVoltammetry
dc.subject.otherMetals
dc.titleVoltammetric lability of multiligand complexes: the case of ML2
dc.typeinfo:eu-repo/semantics/article
dc.date.updated2015-11-10T10:41:39Z
dc.identifier.idgrec002008
dc.type.versioninfo:eu-repo/semantics/acceptedVersion
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.identifier.doihttps://doi.org/10.1016/j.jelechem.2004.04.017


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