Influence of the settling of the resin beads on diffusion gradients in thin films measurements
Altier Infantes, Alexandra
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Binding resin beads used in DGT (Diffusion Gradients in Thin films) tend to settle to one side of the resin during casting. This phenomenon might be relevant for metal accumulation when partially labile complexes dominate the metal speciation, especially after recognizing the important role played by complex dissociation in the resin domain. The influence of the inhomogeneity of the binding agent distribution on metal accumulation is here assessed by numerical simulation of DGT devices with binding beads in only one half of the resin disc, as a reasonable model of the standard resin discs. Results indicate that a decrease in mass accumulation of less than 13% can arise in these inhomogeneous devices (as compared with an ideal disc with homogeneous dispersion of the resin beads) when complexes with stability constant K<1E2m3 mol−1 (K<1E5 L mol−1) dominate the metal speciation. The loss increases as K increases, but the percentage of mass loss always remains lower than the volume fraction of resin disc without beads. For very labile or inert complexes, the impact of the inhomogeneous distribution of binding resin beads is negligible. As kinetic dissociation constants of complexes can be estimated from the distribution of the metal accumulation in a DGT device with a stack of two resin discs, the influence of the inhomogeneity on the recovered kinetic constant is also assessed. For the cases studied, the recovered kinetic dissociation constant, kd,recoveredkd,recovered, retains the correct order of magnitude, being related to the true kd by kd ≈ f −1 x kd(recovered), quite independently of K and kd values, being f the fraction of volume of the resin disc where resin beads are dispersed.
Is part ofAnalytica Chimica Acta, 2015, vol. 885, p. 148-155
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Accumulation of Mg to Diffusive Gradients in Thin Films (DGT) devices: Kinetic and thermodynamic effects of the ionic strength Altier Infantes, Alexandra; Jiménez-Piedrahita, Martín; Rey Castro, Carlos; Cecilia Averós, Joan; Galceran i Nogués, Josep; Puy Llorens, Jaume (American Chemical Society, 2016-09-23)Availability of magnesium is a matter of concern due to its role in many environmental and biological processes. Diffusive Gradients in Thin Films (DGT) devices can measure Mg availability in situ. This work shows that Mg ...
Extending the use of Diffusive Gradients in Thin Films (DGT) to solutions where competition, saturation, and kinetic effects are not negligible Jiménez-Piedrahita, Martín; Altier Infantes, Alexandra; Cecilia Averós, Joan; Puy Llorens, Jaume; Galceran i Nogués, Josep; Rey Castro, Carlos; Zhang, Hao; Davison, William (American Chemical Society, 2017-06-20)DGT (Diffusion Gradients in Thin films) was designed to sample trace metals in situ at their natural concentrations. The setup and the experimental deployment conditions were established to allow interpretation of a linear ...
Altier Infantes, Alexandra; Jiménez-Piedrahita, Martín; Uribe Kaffure, Ramiro; Rey Castro, Carlos; Cecilia Averós, Joan; Galceran i Nogués, Josep; Puy Llorens, Jaume (CSIRO Publishing, 2018)Natural waters contain mixtures of ligands, which collectively affect the availability of trace metals. The individual contribution of each complex to the overall metal flux received by a sensor can be described in terms ...