Physico-chemical and mechanical properties of microencapsulated phase change material
Giró Paloma, Jessica
Fernández Renna, Ana Inés
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Microencapsulated phase change materials (MPCM) are well known in advanced technologies for the utilization in active and passive systems, which have the capacity to absorb and slowly release the latent heat involved in a phase change process. Microcapsules consist of little containers, which are
made of polymer on the outside, and paraffin wax as PCM in the inside. The use of microencapsulated PCM has many advantages as microcapsules can handle phase change materials as core allowing the preparation of slurries. However there are some concerns about cycling of MPCM slurries because of the breakage of microcapsules during charging/discharging and the subsequent loss of effectiveness. This phenomenon motivates the study of the mechanical response when a force is applied to the microcapsule. The maximum force that Micronal® DS 5001 can afford before breaking was determined by Atomic Force Microscopy (AFM). To simulate real conditions in service, assays were done at different temperatures: with the PCM in solid state at 25 ºC, and with the PCM melted at 45 ºC and 80 ºC. To better understand the behavior of these materials, Micronal® DS 5001 microcapsules were characterized using different physic-chemical techniques. Microcapsules Fourier Transform Infrared Spectroscopy (FT-IR) results showed the main vibrations corresponding to acrylic groups of the outside polymer. Thermal stability was studied by Thermogravimetrical Analysis (TGA), and X-ray Fluorescence (XRF) was used to characterize the resulting inorganic residue. The thermal properties were determined using Differential Scanning Calorimetry (DSC) curves. Particles morphology was studied with Scanning Electron Microscopy (SEM) and Mie method was used to evaluate the particle size distribution. Samples had a bimodal distribution of size and were formed by two different particles sizes: agglomerates of 150 lm diameter formed by small particles of 6 lm. Atomic Force Microscopy in nanoindentation mode was used to evaluate the elastic response of the particles at different temperatures. Different values of effective modulus Eeff were calculated for agglomerates and small particles. It was observed that stiffness depended on the temperature assay and particle size, as agglomerates showed higher stiffness than small particles, which showed an important decrease in elastic properties at 80 ºC.
Is part ofApplied Energy, 2013, vol. 109, p. 441–448
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Giró Paloma, Jessica; Barreneche Güerisoli, Camila; Martínez, Mònica; Šumiga, Boštjan; Cabeza, Luisa F.; Fernández Renna, Ana Inés (Elsevier, 2015)Phase change slurries (PCS) consist on a carrier fluid binary system, where water is mostly used as continuous phase and micro-encapsulated phase change materials (MPCM) are used as dispersed phase. PCS are used in Thermal ...
Giró Paloma, Jessica; Barreneche Güerisoli, Camila; Delgado, Mónica; Martínez, Mònica; Fernández Renna, Ana Inés; Cabeza, Luisa F. (Elsevier, 2014)The present work studies a Phase Change Slurry (PCS) as a proposed Thermal Energy Storage (TES) medium. Microencapsulation is an advanced technology to implement PCMs (Phase Change Material) avoiding leakage from ...
Giró Paloma, Jessica; Barreneche Güerisoli, Camila; Martínez, Mònica; Sumiga, Bostjan; Fernández Renna, Ana Inés; Cabeza, Luisa F. (Elsevier, 2016)Thermal energy storage (TES) is one method to accumulate thermal energy. In TES, latent heat storage using phase change materials (PCM) has attracted a lot of interest, recently. Phase change slurries (PCS) consist on a ...