Identification of carotenoids using mass spectrometry

Rivera Vélez, Sol Maiam; Christou, Paul; Canela i Garayoa, Ramon

doi:https://doi.org/10.1002/mas.21390

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Issue date

2014

Author

Rivera Vélez, Sol Maiam

Christou, Paul

Canela i Garayoa, Ramon

Suggested citation

Rivera Vélez, Sol Maiam; Christou, Paul; Canela i Garayoa, Ramon; . (2014) . Identification of carotenoids using mass spectrometry. Mass Spectrometry Reviews, 2013, núm. 9999, p. 1-20. https://doi.org/10.1002/mas.21390.

Abstract

The present review compiles positive MS fragmentation data of selected carotenoids obtained using various ionization techniques and matrices. In addition, new experimental data from the analysis of carotenoids in transgenic maize and rice callus are provided. Several carotenes and oxygen-functionalized

carotenoids containing epoxy, hydroxyl, and ketone groups were ionized by atmospheric pressure chemical ionization (APCI)-tandem mass spectrometry (MS/MS) in positive ion mode. Thus, on the basis of the information obtained from the literature and our own experiments, we identified characteristic carotenoid ions that can be associated to functional groups in the structures of these compounds. In addition, pigments with a very similar structure were differentiated through comparison of the intensities of their fragments. The data provide a basis for the structural elucidation of carotenoids by mass spectrometry (MS).

URI

http://hdl.handle.net/10459.1/47218

DOI

https://doi.org/10.1002/mas.21390

Is part of

Mass Spectrometry Reviews, 2013, núm. 9999, p. 1-20