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dc.contributor.authorSolarte Orozco, Carmen Eugenia
dc.contributor.authorEscribà i Gelonch, Marc
dc.contributor.authorEras i Joli, Jordi
dc.contributor.authorVillorbina Noguera, Gemma
dc.contributor.authorCanela i Garayoa, Ramon
dc.contributor.authorBalcells Fluvià, Mercè
dc.date.accessioned2011-07-01T08:14:11Z
dc.date.available2011-07-01T08:14:11Z
dc.date.issued2011
dc.identifier.issn1420-3049
dc.identifier.urihttp://hdl.handle.net/10459.1/41524
dc.description.abstractThe anticipated worldwide increase in biodiesel production will result in an accumulation of glycerol for which there are insufficient conventional uses. The surplus of this by-product has increased rapidly during the last decade, prompting a search for new glycerol applications. We describe here the synthesis of dissymmetric chlorohydrin esters from symmetric 1,3-dichloro-2-propyl esters obtained from glycerol. We studied the influence of two solvents: 1,4-dioxane and 1-butanol and two bases: sodium carbonate and 1-butylimidazole, on the synthesis of dissymmetric chlorohydrin esters. In addition, we studied the influence of other bases (potassium and lithium carbonates) in the reaction using 1,4-dioxane as the solvent. The highest yield was obtained using 1,4-dioxane and sodium carbonate.ca_ES
dc.description.sponsorshipThis work was supported by a Grant-in-Aid from the Secretaría de Estado de Política Cientifíca y Tecnológica of the Spanish Ministry of Education and Culture (contract Grant No.: CTQ2009-14699- C02-01). The authors are grateful to the Comissionat per a Universitats i Recerca del Departament d’Innovació, Universitats i Empresa de la Generalitat de Catalunya and to the European social Fund (EFS) for the FI grant of Carmen Solarte Orozco.
dc.language.isoengca_ES
dc.publisherMolecular Diversity Preservation Internationalca_ES
dc.relationMICINN/PN2008-2011/CTQ2009-14699-C02-01
dc.relation.isformatofReproducció del document publicat a https://doi.org/10.3390/molecules16032065ca_ES
dc.relation.ispartofMolecules, 2011, vol. 16, núm. 3, p. 2065-2074ca_ES
dc.rightscc-by, (c) Solarte et al., 2011ca_ES
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/deed.caca_ES
dc.subjectGlycerolca_ES
dc.subjectChlorohydrin estersca_ES
dc.subjectDissymmetryca_ES
dc.subject1-butanolca_ES
dc.subject.otherGlicerinaca_ES
dc.subject.otherÈstersca_ES
dc.titleFrom symmetric glycerol derivatives to dissymmetric chlorohydrinsca_ES
dc.typearticleca_ES
dc.identifier.idgrec016310
dc.type.versionpublishedVersionca_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.identifier.doihttps://doi.org/10.3390/molecules16032065


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cc-by, (c) Solarte et al., 2011
Except where otherwise noted, this item's license is described as cc-by, (c) Solarte et al., 2011