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dc.contributor.authorOromí Farrús, Mireia
dc.contributor.authorEras i Joli, Jordi
dc.contributor.authorSala i Martí, Núria
dc.contributor.authorTorres i Grifo, Mercè
dc.contributor.authorCanela i Garayoa, Ramon
dc.date.accessioned2010-04-30T12:43:05Z
dc.date.available2010-04-30T12:43:05Z
dc.date.issued2009
dc.identifier.issn1420-3049
dc.identifier.urihttp://hdl.handle.net/10459.1/370
dc.description.abstractPreparation of (S)-1-chloro-2-octanol and (S)-1-bromo-2-octanol was carried out by the enzymatic hydrolysis of halohydrin palmitates using biocatalysts. Halohydrin palmitates were prepared by various methods from palmitic acid and 1,2-octanediol. A tandem hydrolysis was carried out using lipases from Candida antarctica (Novozym® 435), Rhizomucor miehei (Lipozyme IM), and “resting cells” from a Rhizopus oryzae strain that was not mycotoxigenic. The influence of the enzyme and the reaction medium on the selective hydrolysis of isomeric mixtures of halohydrin esters is described. Novozym® 435 allowed preparation of (S)-1-chloro-2-octanol and (S)-1-bromo-2-octanol after 1–3 h ofreaction at 40 °C in [BMIM][PF6].ca_ES
dc.language.isoengca_ES
dc.publisherMolecular Diversity Preservation Internationalca_ES
dc.relation.isformatofReproducció del document publicat a https://doi.org/10.3390/molecules14104275ca_ES
dc.relation.ispartofMolecules, 2009, vol. 14, núm. 10, p. 4275-4283ca_ES
dc.rightscc-by, (c) Oromí-Farrús et al., 2009ca_ES
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/deed.caca_ES
dc.subject(S)-1-bromomethyl-1-heptanolca_ES
dc.subject(S)-1-chloromethyl-1-heptanolca_ES
dc.subjectLipasesca_ES
dc.subjectEnzymatic resolutionca_ES
dc.subject.otherLipasaca_ES
dc.titlePreparation of (S)-1-halo-2-octanols using ionic liquids and biocatalystsca_ES
dc.typearticleca_ES
dc.identifier.idgrec014373
dc.type.versionpublishedVersionca_ES
dc.rights.accessRightsopen access
dc.identifier.doihttps://doi.org/10.3390/molecules14104275


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cc-by, (c) Oromí-Farrús et al., 2009
Except where otherwise noted, this item's license is described as cc-by, (c) Oromí-Farrús et al., 2009